Molecular Geometry and Bonding Theories

Get Started. It's Free
or sign up with your email address
Molecular Geometry and Bonding Theories by Mind Map: Molecular Geometry and Bonding Theories

1. ---

2. Types of Chemical Bonds**

3. - **Ionic Bonds**

3.1. - Transfer of electrons

3.2. - Forms between metals and non-metals

3.3. - Examples: NaCl, MgO

4. - **Covalent Bonds**

4.1. - Sharing of electrons

4.2. - Can be polar or nonpolar

4.3. - Examples: H₂O (polar), CH₄ (nonpolar)

5. - **Metallic Bonds**

5.1. - Sea of electrons

5.2. - Explains properties like conductivity and malleability

6. : Lewis Symbols and Octet Rule**

7. - **Octet Rule**

7.1. - Atoms strive to complete 8 valence electrons

7.2. - Exceptions:

7.2.1. - Incomplete octets (e.g., Be, B compounds)

7.2.2. - Expanded octets (e.g., PCl₅, SF₆)

8. - **Lewis Symbols**

8.1. - Representation of valence electrons around atoms

9. : Bond Polarity and Electronegativity**

10. - **Electronegativity**

10.1. - Measure of an atom’s ability to attract shared electrons

10.2. - Trends: Increases across a period, decreases down a group

11. - **Bond Polarity**

11.1. - Determined by electronegativity difference

11.1.1. - Polar bonds (e.g., H-Cl)

11.1.2. - Nonpolar bonds (e.g., Cl-Cl)

12. Lewis Structures and Resonance Structures**

13. - **Drawing Lewis Structures**

13.1. - Show bonding and lone pairs

13.2. - Follow the octet rule (with exceptions)

14. - **Resonance Structures**

14.1. - Molecules with delocalized electrons

14.2. - Example: O₃ (ozone)

15. : Molecular Shapes and VSEPR Model**

16. - **VSEPR Model**

16.1. - Valence Shell Electron Pair Repulsion Theory

16.2. - Predicts 3D molecular geometry based on electron pair repulsion

16.3. - Examples:

16.3.1. - Linear: CO₂

16.3.2. - Bent: H₂O

16.3.3. - Tetrahedral: CH₄

17. - **Molecular Shapes**

17.1. - Dependent on the number of bonding and lone pairs

18. Bond Strength (Bond Enthalpy) and Multiple Bonds**

19. - **Bond Strength**

19.1. - Defined by bond enthalpy (energy required to break a bond)

19.2. - Triple bonds > Double bonds > Single bonds

20. - **Multiple Bonds**

20.1. - Double and triple bonds have higher bond strength and shorter bond length

21. Hybrid Orbitals and Molecular Orbitals**

22. - **Hybridization**

22.1. - Mixing of atomic orbitals to form hybrid orbitals

22.2. - Types: sp, sp², sp³, sp³d, sp³d²

23. - **Molecular Orbitals**

23.1. - Constructed from the combination of atomic orbitals

23.2. - Bonding vs. antibonding orbitals