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1. Pre-Synthesis

1.1. Ferric species

1.2. Better crystals

1.2.1. Chloride inevitable due to HCl in reaction

1.2.2. Reduction post-synthesis necessary if ferrous porphyrin desired.

1.2.2.1. Some methods are not applicable to MOFs.

2. Axial Ligand Exchange

2.1. Chloride Abstraction

2.2. Thiolate Installation

2.3. Non-coorindating ligands

3. Iron Installation

3.1. Post-Synthesis

3.1.1. Mandatory for ferrous - ferric chloride WILL form during MOF synthesis.

4. Characterization

4.1. Fe centers

4.1.1. Coordination number

4.1.1.1. 4

4.1.1.2. 5

4.1.1.3. 6

4.1.2. Ligands

4.1.3. Oxidation state

4.1.4. Magnetic properties

4.2. MOF

4.2.1. Structure

4.2.1.1. PXRD

5. Methods

5.1. EPR

5.2. Mossbauer

5.3. Diffuse Reflectance

5.4. NMR

5.5. Crystallography

5.5.1. SCXRD

5.5.2. PXRD

5.6. Electrochemistry

5.6.1. CV